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The solubility of silver chloride _______________ when dilute nitric is added to it.


A) increases
B) decreases
C) does not change
D) first increases,then decreases
E) first decreases,then increases

F) B) and E)
G) D) and E)

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A 35.0-mL sample of 0.20 M LiOH is titrated with 0.25 M HCl.What is the pH of the solution after 23.0 mL of HCl have been added to the base?


A) 1.26
B) 1.67
C) 12.33
D) 12.74
E) 13.03

F) A) and C)
G) A) and D)

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What will be the effect of adding 0.5 mL of 0.1 M NaOH to 100 mL of an acetate buffer in which [CH3COOH] = [CH3COO-] = 0.5 M?


A) The pH will increase slightly.
B) The pH will increase significantly.
C) The pH will decrease slightly.
D) The pH will decrease significantly.
E) Since it is a buffer solution,the pH will not be affected.

F) B) and D)
G) C) and D)

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Calculate the solubility of strontium fluoride,SrF2,in pure water.Ksp = 2.6 ×\times 10-9


A) 1.4 ×\times 10-3 M
B) 3.4 ×\times 10-4 M
C) 8.7 ×\times 10-4 M
D) 5.l ×\times 10-5 M
E) < 1.0 ×\times 10-5 M

F) A) and E)
G) B) and E)

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Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak acid (0.10 mol L-1) with a strong base of the same concentration?


A)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak acid (0.10 mol L<sup>-1</sup>) with a strong base of the same concentration? A)    B)    C)    D)    E)
B)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak acid (0.10 mol L<sup>-1</sup>) with a strong base of the same concentration? A)    B)    C)    D)    E)
C)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak acid (0.10 mol L<sup>-1</sup>) with a strong base of the same concentration? A)    B)    C)    D)    E)
D)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak acid (0.10 mol L<sup>-1</sup>) with a strong base of the same concentration? A)    B)    C)    D)    E)
E)
Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak acid (0.10 mol L<sup>-1</sup>) with a strong base of the same concentration? A)    B)    C)    D)    E)

F) None of the above
G) C) and D)

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The lab technician Anna Lytic adds 2.20 mol KOH to 1.00 L of 0.5 M Al(NO3) 3.What is the concentration of aluminum ions after the aluminum nitrate has reacted with the potassium hydroxide? Kf = 3.0 ×\times 1033 for Al(OH) 4-


A) 1.8 ×\times 10-7 M
B) 9.l ×\times 10-18 M
C) 1.0 ×\times 10-31 M
D) 3.3 ×\times 10-34 M
E) 7.l ×\times 10-36 M

F) B) and E)
G) A) and E)

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When a weak acid is titrated with a weak base,the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0.
D) is determined by the sizes of Ka and Kb.
E) is no longer affected by addition of base.

F) B) and C)
G) C) and E)

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A buffer is prepared by adding 300.0 mL of 2.0 M NaOH to 500.0 mL of 2.0 M CH3COOH.What is the pH of this buffer? Ka = 1.8 ×\times 10-5


A) 4.57
B) 4.52
C) 4.87
D) 4.92
E) 4.97

F) None of the above
G) C) and D)

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Which of the following indicators would be the best to use when 0.050 M benzoic acid (Ka = 6.6 ×\times 10-5) is titrated with 0.05 M NaOH?


A) bromphenol blue,pH range: 3.0-4.5
B) bromcresol green,pH range: 3.8-5.4
C) alizarin,pH range: 5.7-7.2
D) phenol red,pH range: 6.9-8.2
E) phenolphthalein,pH range: 8.0-10.1

F) A) and D)
G) D) and E)

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Buffer solutions with the component concentrations shown below were prepared.Which of them should have the lowest pH?


A) [CH3COOH] = 0.25 M,[CH3COO-] = 0.25 M
B) [CH3COOH] = 0.75 M,[CH3COO-] = 0.75 M
C) [CH3COOH] = 0.75 M,[CH3COO-] = 0.25 M
D) [CH3COOH] = 0.25 M,[CH3COO-] = 0.75 M
E) [CH3COOH] = 1.00 M,[CH3COO-] = 1.00 M

F) A) and E)
G) A) and B)

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Write the ion product expression for silver sulfide,Ag2S.


A)
Write the ion product expression for silver sulfide,Ag<sub>2</sub>S. A)    B)    C)    D)    E)
B)
Write the ion product expression for silver sulfide,Ag<sub>2</sub>S. A)    B)    C)    D)    E)
C)
Write the ion product expression for silver sulfide,Ag<sub>2</sub>S. A)    B)    C)    D)    E)
D)
Write the ion product expression for silver sulfide,Ag<sub>2</sub>S. A)    B)    C)    D)    E)
E)
Write the ion product expression for silver sulfide,Ag<sub>2</sub>S. A)    B)    C)    D)    E)

F) None of the above
G) D) and E)

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The solubility of salt MX (solubility product constant Ksp)in water will always be greater than that of salt MX3 (solubility product constant Ksp)provided that Ksp > K'sp.

A) True
B) False

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Increasing the concentrations of the components of a buffer solution will increase the buffer range.

A) True
B) False

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A buffer is prepared by adding 100 mL of 0.50 M sodium hydroxide to 100 mL of 0.75 M propanoic acid.Is this a buffer solution,and if so,what is its pH?


A) It is a buffer,pH > pKa of propanoic acid.
B) It is a buffer,pH < pKa of propanoic acid.
C) It is a buffer,pH = pKa of propanoic acid.
D) It is a buffer,pH = pKb of sodium propanoate.
E) Since sodium hydroxide is a strong base,this is not a buffer.

F) A) and E)
G) A) and D)

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A

A phosphate buffer (H2PO4-/HPO42-) has a pH of 8.3.Which of the following changes will cause the pH to increase?


A) dissolving a small amount of Na2HPO4
B) dissolving a small amount of NaH2PO4
C) adding a small amount of dilute hydrochloric acid
D) adding a small amount of dilute phosphoric acid
E) making the buffer more concentrated by removing some water

F) A) and E)
G) B) and D)

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Formic acid is a monoprotic acid with a Ka value of 1.8 ×\times 10-4 at 25°C. a.Calculate the pH of a 0.200 mol L-1 solution of the acid,making any reasonable approximations. b.If 0.0050 mol of NaOH is added to 100.mL of the solution in (a),calculate the pH of the resultant buffer.

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a.2.22 b.3.27

The concentration of the complex ion in each of following solutions is 1.00 M.In which of the solutions will the concentration of the uncomplexed metal ion be the greatest? Hg(CN) 42- Kf = 9.3 ×\times 1038 Be(OH) 42- Kf = 4.0 ×\times 1018 Zn(OH) 42- Kf = 3.0 ×\times 1015 Cu(NH3) 42+ Kf = 5.6 ×\times 1011 CdI42- Kf = 1.0 ×\times 106


A) Hg2+
B) Be2+
C) Zn2+
D) Cu2+
E) Cd2+

F) A) and E)
G) A) and D)

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What is the pH of a buffer that consists of 0.45 M CH3COOH and 0.35 M CH3COONa? Ka = 1.8 ×\times 10-5


A) 4.49
B) 4.64
C) 4.85
D) 5.00
E) 5.52

F) A) and B)
G) A) and C)

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Propanoic acid (CH3CH2COOH)has a Ka of 1.34 ×\times 10-5.A 25.00 mL sample of 0.1000 mol L-1 propanoic acid (in flask)is titrated with 0.1000 mol L-1 NaOH solution,added from a buret.Carry out the calculations of the quantities indicated below. a.The pH after 0.00 mL of NaOH are added. b.The pH after 15.00 mL of NaOH are added. c.The hydroxide ion concentration after 26.00 mL of NaOH are added.

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a.2.94
b.5.05
c.1.96...

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Write the ion product expression for magnesium fluoride,MgF2.


A)
Write the ion product expression for magnesium fluoride,MgF<sub>2</sub>. A)    B)    C)    D)    E)
B)
Write the ion product expression for magnesium fluoride,MgF<sub>2</sub>. A)    B)    C)    D)    E)
C)
Write the ion product expression for magnesium fluoride,MgF<sub>2</sub>. A)    B)    C)    D)    E)
D)
Write the ion product expression for magnesium fluoride,MgF<sub>2</sub>. A)    B)    C)    D)    E)
E)
Write the ion product expression for magnesium fluoride,MgF<sub>2</sub>. A)    B)    C)    D)    E)

F) A) and E)
G) All of the above

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B

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