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For the reaction shown below,N2O4 and NO2 have equilibrium concentrations,[N2O4]eq = 2.160 × 10-4 and [NO2]eq = 1.001 × 10-3,respectively.The equilibrium constant,Kc,for this reaction equals ________. N2O4(g)⇌ 2 NO2(g)

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At a certain temperature,Kc equals 1.4 × 102 for the reaction: 2 CO(g) + O2(g) ⇌ 2 CO2(g) . If a 2.50-L flask contains 0.400 mol of CO2 and 0.100 mol of O2 at equilibrium,how many moles of CO are also present in the flask?


A) 0) 422 mol
B) 0) 169 mol
C) 0) 107 mol
D) 0) 0114 mol

E) C) and D)
F) B) and C)

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Which statement is true for a reaction with Kc equal to 2.43 × 10-12?


A) Increasing the temperature will not change the value of Kc.
B) There are appreciable concentrations of both reactants and products.
C) The reaction proceeds hardly at all towards completion.
D) The reaction proceeds nearly all the way to completion.

E) B) and C)
F) A) and D)

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The following pictures represent the initial state and the equilibrium state for the gaseous state reaction of A2 molecules (shaded spheres) with B atoms (unshaded spheres) to give AB molecules. The following pictures represent the initial state and the equilibrium state for the gaseous state reaction of A<sub>2</sub> molecules (shaded spheres) with B atoms (unshaded spheres) to give AB molecules.   -If the volume of the equilibrium mixture is decreased,what will happen to the number of AB molecules and the number of B atoms? A) The number of AB molecules and the number of B atoms will both decrease. B) The number of AB molecules will increase;the number of B atoms will decrease. C) The number of AB molecules will decrease;the number of B atoms will increase. D) The number of AB molecules and the number of B atoms will both increase. -If the volume of the equilibrium mixture is decreased,what will happen to the number of AB molecules and the number of B atoms?


A) The number of AB molecules and the number of B atoms will both decrease.
B) The number of AB molecules will increase;the number of B atoms will decrease.
C) The number of AB molecules will decrease;the number of B atoms will increase.
D) The number of AB molecules and the number of B atoms will both increase.

E) All of the above
F) None of the above

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Kc is 1.67 × 1020 at 25°C for the formation of iron(III) oxalate complex ion: Fe3+(aq) + 3 C2O42-(aq) ⇌ [Fe(C2O4) 3]3-(aq) . If 0.0200 M Fe3+ is initially mixed with 1.00 M oxalate ion,what is the concentration of Fe3+ ion at equilibrium?


A) 1) 44 × 10-22 M
B) 0) 0100 M
C) 8) 35 × 1019 M
D) 6) 94 × 1021 M

E) A) and B)
F) A) and C)

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The following pictures represent the equilibrium state for four different reactions of the type A2 + X2 ⇌ 2 AX (X = B,C,D,E) .A atoms are unshaded.X atoms are shaded. The following pictures represent the equilibrium state for four different reactions of the type A<sub>2</sub> + X<sub>2</sub> ⇌ 2 AX (X = B,C,D,E) .A atoms are unshaded.X atoms are shaded.   -Which reaction has the smallest equilibrium constant? A) A<sub>2</sub> + B<sub>2</sub> ⇌ 2 AB B) A<sub>2</sub> + C<sub>2</sub> ⇌ 2 AC C) A<sub>2</sub> + D<sub>2</sub> ⇌ 2 AD D) A<sub>2</sub> + E<sub>2</sub> ⇌ 2 AE -Which reaction has the smallest equilibrium constant?


A) A2 + B2 ⇌ 2 AB
B) A2 + C2 ⇌ 2 AC
C) A2 + D2 ⇌ 2 AD
D) A2 + E2 ⇌ 2 AE

E) All of the above
F) A) and B)

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For the reaction shown below the value of Kp is ________ than the value of Kc,because Δn = ________. N2O4(g)⇌ 2 NO2(g)

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Which equilibrium below is homogeneous?


A) BaSO4(s) ⇌ Ba2+(aq) + SO42-(aq)
B) 2 H2O2(l) ⇌ 2 H2O(l) + O2(g)
C) NH4NO3(s) ⇌ N2O(g) + 2 H2O(g)
D) 2 CO(g) + O2(g) ⇌ 2 CO2(g)

E) A) and B)
F) A) and C)

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A reaction reaches dynamic equilibrium at a given temperature when


A) the amount of products exceeds the amount of reactants.
B) kfwd equals krev.
C) opposing reactions cease and the system is static.
D) the relative amounts of reactants and products are constant and ratefwd = raterev.

E) B) and C)
F) A) and D)

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If Kc = 2.0 x 1033 at 25°C,for the following reaction: H2(g) + Cl2(g) ⇌ 2 HCl(g) ,then find Kp at the same temperature.


A) 8) 2 × 1031
B) 9) 7 × 1032
C) 2) 0 × 1033
D) 4) 9 × 1034

E) B) and C)
F) A) and D)

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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of increasing the temperature of the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.

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The reaction CaCO3(s)⇌ CaO(s)+ O2(g)is endothermic 298 K.The effect of adding additional CaO to the system at equilibrium will ________ (decrease,increase,have no effect on)the total quantity of CaCO3 once equilibrium is reestablished.

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The equilibrium constant Kc for the reaction HF(aq) + H2O(l) ⇌ H3O+(aq) +F-(aq) is 3.5 × 10-4.What is the equilibrium concentration of H3O+ if the initial concentration of HF is 1.0 M?


A) 1) 0 M
B) 3) 5 × 10-2 M
C) 1) 9 × 10-2 M
D) 1) 9 × 10-4 M

E) A) and C)
F) All of the above

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Write the equilibrium equation for the reverse reaction: 2 CH4 (g) + 3 O2 (g) ⇌ 2 CO (g) + 4 H2O (g)


A) Kc´ = Write the equilibrium equation for the reverse reaction: 2 CH<sub>4</sub> (g) + 3 O<sub>2</sub> (g) ⇌ 2 CO (g) + 4 H<sub>2</sub>O (g)  A) K<sub>c</sub>´ =   B) K<sub>c</sub>´ =   C) K<sub>c</sub>´ =   D) K<sub>c</sub>´ =
B) Kc´ = Write the equilibrium equation for the reverse reaction: 2 CH<sub>4</sub> (g) + 3 O<sub>2</sub> (g) ⇌ 2 CO (g) + 4 H<sub>2</sub>O (g)  A) K<sub>c</sub>´ =   B) K<sub>c</sub>´ =   C) K<sub>c</sub>´ =   D) K<sub>c</sub>´ =
C) Kc´ = Write the equilibrium equation for the reverse reaction: 2 CH<sub>4</sub> (g) + 3 O<sub>2</sub> (g) ⇌ 2 CO (g) + 4 H<sub>2</sub>O (g)  A) K<sub>c</sub>´ =   B) K<sub>c</sub>´ =   C) K<sub>c</sub>´ =   D) K<sub>c</sub>´ =
D) Kc´ = Write the equilibrium equation for the reverse reaction: 2 CH<sub>4</sub> (g) + 3 O<sub>2</sub> (g) ⇌ 2 CO (g) + 4 H<sub>2</sub>O (g)  A) K<sub>c</sub>´ =   B) K<sub>c</sub>´ =   C) K<sub>c</sub>´ =   D) K<sub>c</sub>´ =

E) C) and D)
F) None of the above

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Given the reaction: 2 HI ⇌ H2 + I2.If Kc' for the reverse reaction is 1.85 × 10-2 at 425°C,what is Kc for the forward reaction at the same temperature?


A) -1.85 × 10-2
B) 1) 85 × 10-2
C) 3) 70 × 10-2
D) 54.1

E) A) and B)
F) B) and C)

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Write the equilibrium equation for the reverse reaction: 2 CH4(g) + 3 O2(g) ⇌ 2 CO(g) + 4 H2O(g)


A) Kp' = Write the equilibrium equation for the reverse reaction: 2 CH<sub>4</sub>(g) + 3 O<sub>2</sub>(g) ⇌ 2 CO(g) + 4 H<sub>2</sub>O(g)  A) K<sub>p</sub><sup>'</sup> =   B) K<sub>p</sub><sup>'</sup> =   C) K<sub>p</sub><sup>'</sup> =   D) K<sub>p</sub><sup>'</sup> =
B) Kp' = Write the equilibrium equation for the reverse reaction: 2 CH<sub>4</sub>(g) + 3 O<sub>2</sub>(g) ⇌ 2 CO(g) + 4 H<sub>2</sub>O(g)  A) K<sub>p</sub><sup>'</sup> =   B) K<sub>p</sub><sup>'</sup> =   C) K<sub>p</sub><sup>'</sup> =   D) K<sub>p</sub><sup>'</sup> =
C) Kp' = Write the equilibrium equation for the reverse reaction: 2 CH<sub>4</sub>(g) + 3 O<sub>2</sub>(g) ⇌ 2 CO(g) + 4 H<sub>2</sub>O(g)  A) K<sub>p</sub><sup>'</sup> =   B) K<sub>p</sub><sup>'</sup> =   C) K<sub>p</sub><sup>'</sup> =   D) K<sub>p</sub><sup>'</sup> =
D) Kp' = Write the equilibrium equation for the reverse reaction: 2 CH<sub>4</sub>(g) + 3 O<sub>2</sub>(g) ⇌ 2 CO(g) + 4 H<sub>2</sub>O(g)  A) K<sub>p</sub><sup>'</sup> =   B) K<sub>p</sub><sup>'</sup> =   C) K<sub>p</sub><sup>'</sup> =   D) K<sub>p</sub><sup>'</sup> =

E) None of the above
F) A) and C)

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The pink and blue species below form a violet colored mixture at equilibrium: [Co(H2O) 6]2+ (aq) + 4 Cl- (aq) ⇌ [CoCl4]2- (aq) + 6 H2O (l) (pink) (blue) If the concentration of [Co(H2O) 6]2+ is increased,what happens to the solution?


A) The concentration of [CoCl4]2- increases.
B) The concentration of [CoCl4]2- decreases.
C) The solution becomes colorless.
D) No color change is observed.

E) C) and D)
F) A) and B)

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A reaction in which reactants form products in the forward reaction and products simultaneously form reactants in the reverse reaction is said to be ________.

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If Kc is the equilibrium constant for a forward reaction,2 A⇌ B,what is Kc´ for the reaction 4 A⇌ 2B?


A) If K<sub>c</sub> is the equilibrium constant for a forward reaction,2 A⇌ B,what is K<sub>c</sub>´ for the reaction 4 A⇌ 2B? A)    K<sub>c</sub> B) K<sub>c</sub> C) 2 K<sub>c</sub> D) (K<sub>c</sub>) <sup>2</sup> Kc
B) Kc
C) 2 Kc
D) (Kc) 2

E) A) and B)
F) C) and D)

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Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the reaction: PCl5(g) ⇌ PCl3(g) + Cl2(g) At 250°C,0.250 M PCl5 is added to a flask.If Kc = 1.80,what are the equilibrium concentrations of each gas?


A) [PCl5] = 0.0280 M,[PCl3] = 0.222 M,[Cl2] = 0.222 M
B) [PCl5] = 1.25 M,[PCl3] = 0.474 M,[Cl2] = 0.474 M
C) [PCl5] = 1.80 M,[PCl3] = 1.80 M,[Cl2] = 1.80 M
D) [PCl5] = 2.27 M,[PCl3] = 2.02 M,[Cl2] = 2.02 M

E) A) and D)
F) A) and C)

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